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Team Building
A vital part of succeeding with Thor is knowing where to position him on your team. Thor is primarily a Point Character. This is due to many reasons, the primary one being that he gains more from having two strong supports behind him than the support that he offers. That said, Thor can also function on Second behind a handful of points. This is generally suboptimal, but thor's unique support takes the form of his TAC infinite, two alright assists, and an invulnerable crossover counter from Mighty Smash. This means that, overall, it is generally best to position Thor on point -- but he can still function off-point in a limited capacity.
Notable Supports
Doctor Doom



Doctor Doom is Thor's single best friend, and it's not particularly close. Doom's TACs and DHCs are both very strong and enable Thor to secure kills he might struggle with otherwise. But one underrated aspect of this pairing is the sheer ease Thor has at raw-tagging Doom. He can tag him after any grounded throw (even midscreen) or air magic sequence (corner only), leading to huge damage and meter gain. Thor uses all 3 of Doom's assists well: Plasma Beam is an incredibly strong horizontal coverage tool which he can chain together with Mighty Spark for huge damage, and Hidden Missiles enables incredibly damaging extensions that allow Thor to kill the entire cast and build oodles of meter (on normal bodies). Even rocks is useful for Thor, who can tridash in behind them, though he tends to prefer the other two.
Doctor Strange

Doctor Strange is similarly strong for Thor, with Bolts of Balthakk assist being arguably his single strongest horizontal. Thor can DHC to strange off superjump height Mighty Tornado into a whiffed Seven Rings, which Strange can then convert into a full combo. Together with or in place of Doom, Strange can be an extremely strong partner for Thor.
Rocket Raccoon


Rocket Raccoon is another very strong partner for Thor. Usually placed mid behind a Thor on point, Mad Hopper DHC enables Thor to extend off a raw tag into fully charged Mighty Strike sequences for beaucoup damage and tons of meter. Pendulum and Spitfire are both extremely strong assists for Thor, enabling crazy pickups in the case of Pendulum or strong grounded pressure in the case of Spit. Rocket is a difficult and highly-technical character, but he is undeniably one of Thor's best partners.
Dante

Dante is very powerful in combination with Thor. Jam Session is one of Thor's best assists, with his incredibly strong high-low game and his ability to convert off superjump height jam with relative ease. It also enables very damaging combos and there are several hard tag routes between the two which -- while lacking on damage compared to Doom -- still build tons of meter and allow for interesting setups. What's more, Dante can be vulnerable to rushdown, and having an invulnerable crossover counter in his back pocket makes him much more versatile on defense. Very strong pair and worth playing together.
Vergil
